Hg II ‐Mediated Tl I ‐to‐Tl III Oxidation in Dynamic Pb II /Tl Porphyrin Complexes
نویسندگان
چکیده
منابع مشابه
Spontaneous Tl(I)-to-Tl(III) oxidation in dynamic heterobimetallic Hg(II)/Tl(I) porphyrin complexes.
Strapped heterobimetallic Hg(II)/Tl(I) porphyrin complexes, with both metal ions bridged by the N-core in a dynamic way, undergo spontaneous Tl(I)-to-Tl(III) oxidation leading to a mono-Tl(III) complex and a mixed valence Tl(I)/Tl(III) bimetallic complex. It provides a new opportunity to tune metal ion translocations in bimetallic porphyrin systems.
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ژورنال
عنوان ژورنال: Chemistry – A European Journal
سال: 2018
ISSN: 0947-6539,1521-3765
DOI: 10.1002/chem.201804713